Pythagoras, who is sometimes called the "First Philosopher," studied under Anaximander, Egyptians, Babylonians, and the mystic Pherekydes (from whom Pythagoras acquired a belief in reincarnation); he became the most influential of early Greek mathematicians. He is credited with being first to use axioms and deductive proofs, so his influence on Plato and Euclid may be enormous. He and his students (the "Pythagoreans") were ascetic mystics for whom mathematics was partly a spiritual tool. (Some occultists treat Pythagoras as a wizard and founding mystic philosopher.) Pythagoras was very interested in astronomy and recognized that the Earth was a globe similar to the other planets. He believed thinking was located in the brain rather than heart. The words "philosophy" and "mathematics" are said to have been coined by Pythagoras.
Despite Pythagoras' historical importance I may have ranked him too high: many results of the Pythagoreans were due to his students; none of their writings survive; and what is known is reported second-hand, and possibly exaggerated, by Plato and others. His students included Hippasus of Metapontum, perhaps the famous physician Alcmaeon, Milo of Croton, and Croton's daughter Theano (who may have been Pythagoras's wife). The term "Pythagorean" was also adopted by many disciples who lived later; these disciples include Philolaus of Croton, the natural philosopher Empedocles, and several other famous Greeks. Pythagoras' successor was apparently Theano herself: the Pythagoreans were one of the few ancient schools to practice gender equality.
Pythagoras discovered that harmonious intervals in music are based on simple rational numbers. This led to a fascination with integers and mystic numerology; he is sometimes called the "Father of Numbers" and once said "Number rules the universe." (About the mathematical basis of music, Leibniz later wrote, "Music is the pleasure the human soul experiences from counting without being aware that it is counting." Other mathematicians who investigated the arithmetic of music included Huygens, Euler and Simon Stevin.)
The Pythagorean Theorem was known long before Pythagoras, but he is often credited with the first proof. (Apastambha proved it in India at about the same time, and some theorize that Pythagoras journeyed to India and learned of the proof there.) He also discovered the simple parametric form of Pythagorean triplets (xx-yy, 2xy, xx+yy). Other discoveries of the Pythagorean school include the concepts of perfect and amicable numbers, polygonal numbers, golden ratio (attributed to Theano), the five regular solids (attributed to Pythagoras himself), and irrational numbers (attributed to Hippasus). It is said that the discovery of irrational numbers upset the Pythagoreans so much they tossed Hippasus into the ocean! (Another version has Hippasus banished for revealing the secret for constructing the sphere which circumscribes a dodecahedron.)
The famous successors of Thales and Pythagoras included Parmenides of Elea (ca 515-440 BC), Zeno of Elea (see below), Hippocrates of Chios (see below), Plato of Athens (ca 428-348 BC), Theaetetus (ca 414-369 BC), and Archytas (see below). These early Greeks ushered in a Golden Age of Mathematics and Philosophy unequaled in Europe until the Renaissance. The emphasis was on pure, rather than practical, mathematics. Plato (who ranks #40 on Michael Hart's famous list of the Most Influential Persons in History) decreed that his scholars should do geometric construction solely with compass and straight-edge rather than with "carpenter's tools" like rulers and protractors.
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